Tetra-n-butylammonium iodido(pyrrolidine-1-carbodithioato-κ2 S,S′)(tris-tert-butoxysilanethiolato-κS)cadmate(II)
نویسندگان
چکیده
In the anion of the title compound, (C(16)H(36)N)[Cd(C(5)H(8)NS(2))(C(12)H(27)O(3)SSi)I], the Cd atom is four-coordinated by S,S'-chelating dithio-carbamate, S-donating silanethiol-ate and iodide ligands in a distorted tetrahedral environment . Inter-molecular C-H⋯ S and C-H⋯I inter-actions between cations and anions are present. Two C atoms of a tert-butyl group are disordered over two positions; the site occupancies are ca 0.65 and 0.35.
منابع مشابه
(2,2′-Bipyridine-κ2 N,N′)iodido(piperidine-1-carbodithioato-κ2 S,S′)copper(II)
In the title compound, [Cu(C(6)H(10)NS(2))I(C(10)H(8)N(2))], the Cu(II) ion is coordinated by one iodide ion, two N atoms of the bipyridine ligand and two S atoms from the piperidine-carbodithio-ate ligand in a distorted square-pyramidal environment. π-π stacking inter-actions, with centroid-centroid distances of 3.643 (4) Å, between pyridyl rings of the bipyridyl ligands of neighbouring mol-ec...
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008